In combination with the latest laser ablation technology, the icpTOF can image geological samples at 10x the rates of standard instruments – recording all elements at each pixel with no carryover between successive pixels.
Olga Borovinskaya, Marie Christine Boiron, Leif Summerfield
TOFWERK, Université de Lorraine, ESI
High resolution elemental imaging by LA-ICP-MS can provide insights into the geological history of minerals.
Most current methods for elemental mapping by LA-ICP-MS use quadrupole or sector field mass analyzers that sequentially measure each isotope of interest at each “pixel” in the imaged 2D area. Because measurement time increases linearly with the number of elements recorded, researchers must carefully define which elements to measure for an unknown sample.
The TOFWERK icpTOF uses a time-of-flight mass analyzer that simultaneously measures all isotopes at high speed. It is therefore well-suited for coupling to new laser ablation chambers that generate very short plumes of aerosols per laser pulse and provide higher S/N and imaging speed. This work demonstrates fast mapping of Ge-rich sphalerite at 5 µm resolution using the icpTOF and the recently developed Dual Concentric Injector from ESI. Where standard setups have to step across pixels to obtain a pixel-resolved image, this configuration is able to resolve pixels while running in the fastest possible continuous scanning mode and recording a complete mass spectrum at each pixel.