icpTOF_circle2019

icpTOF是单颗粒多元素分析和快速激光蚀刻成像的理想选择

一台可同时测量所有同位素的电感耦合等离子体质谱仪(ICP-MS)

欢迎询问/样品测量

icpTOF的优越性能

icpTOF电感耦合等离子体-飞行时间质谱耦合了Thermo Scientific公司的 iCAP RQ平台(包含离子源和真空接口)和TOFWERK高性能飞行时间质谱分析仪。iCAP RQ平台提供了多类型的样品进样方式,高强度并稳固的ICP,更加简单的椎体和离子电镜维护程序和Q-cell科技。飞行时间质谱分析仪在保证跟四级管(QMS)同等灵敏度的同时,为icpTOF增加了快速全谱分析,更宽的线性动态范围和高达6000的质量分辨率。鉴于其快速全谱图采集和所有元素同位素的同步分析,icpTOF是单颗粒多元素分析和快速激光蚀刻成像的理想检测器。

  • All the elements. All the time.
    icpTOF记录全谱图以提供回溯分析,因此 您不会错过任何分析物或干扰信号。
  • 高质量分辨率
    icpTOF 2R高达6000的质量分辨率让排除干扰离子更加容易。
  • 精确的同位素比率
    icpTOF可同时测量所有同位素,从而最大程度上消除离子源和进样过程扰动对测量结果的影响。分析精度趋近于统计限制。
  • 高速检测
    icpTOF每隔30微秒就可记录一张全谱图,使其成为快速瞬态信号(如单个纳米颗粒,流体包裹体和单激光脉冲烧蚀)的最佳检测器。


网络课程:icpTOF基础知识和应用案例介绍

下载icpTOF单颗粒分析案例彩页
下载icpTOF激光蚀刻成像案例彩页

 

icpTOF和icpTOF 2R

icpTOF和icpTOF 2R 耦合了Thermomo Scientific公司的 iCAP RQ平台(包含离子源和真空接口)和TOFWERK高性能飞行时间质谱分析仪。icpTOF 2R搭配一款更长的飞行时间模块,提供高达6000的质量分辨率。icpTOF 2R是对同标称质量的离子分离要求较高的分析案例的理想选择。

 

Mass Resolving Power

(dm/m at FWHM)

Sensitivity

(cps/ppb for 238U)

All Element Analysis

 

icpTOF300050000Yes
icpTOF 2R600030000Yes
下载完整的icpTOF规格表格

 

增长的离子飞行时间带来更好的质量分辨能力

  • 这两款icpTOF都配备了支持Q-cell碰撞/反应技术的iCAP RQ平台(蓝色),有效降低复杂基底可能带来的干扰
  • icpTOF 2R搭配的飞行时间模块(黄色)长度是icpTOF的两倍,大大提升了仪器的质量分辨能力

 

‘陷波’技术有效衰减等离子体和样品基底相关的离子强度

铪含量较高的'Plesovice'锆石的激光脉冲烧蚀实验信号。‘陷波’技术用来将28 -硅, 40 -氩气等离子体, 90 -锆石和 179 -铪等信号控制在10mV以下。

 

 

icpTOF 发表文献

2018

  1. Gundlach-Graham, A., et al. High‐Resolution, Quantitative Element Imaging of an Upper Crust, Low‐Angle Cataclasite (Zuccale Fault, Northern Apennines) by Laser Ablation ICP Time‐of‐Flight Mass Spectrometry. Geostandards and Geoanalytical Research, 2018. In FocusDOI: 10.1111/ggr.12233
  2. Ohata, Masaki, and Hiroyuki Hagino. Examination on simultaneous multi-element isotope ratio measurement by inductively coupled plasma time of flight mass spectrometry. International Journal of Mass Spectrometry. 2018. In FocusDOI:10.1016/j.ijms.2018.03.003
  3. Gundlach-Graham, Alexander, An Elemental Regeneration, The Analytical Scientist, 2018. URL Link
  4. Naasz S., et al. Multi-element analysis of single nanoparticles by ICP-MS using quadrupole and time-of-flight technologies, Journal of Analytical Atomic Spectrometry, 2018. In FocusDOI:10.1039/C7JA00399D
  5. Gondikas, A., et al., Where is the nano? Analytical approaches for the detection and quantification of TiO 2 engineered nanoparticles in surface waters, Environmental Science: Nano 2018.  In Focus | DOI:10.1039/c7en00952f
  6. Hendriks, L., et al., Analysis of Inorganic Nanoparticles by Single-Particle Inductively Coupled Plasma Time-of-Flight Mass Spectrometry, CHIMIA International Journal for Chemistry, 2018. In FocusDOI: 10.2533/chimia.2018.221

2017

  1. Hagino, Hiroyuki et. al., Application of ICP-TOFMS for Real-Time Measurement of Trace Elements in Automotive Exhaust Particulate Matters from Engine Oil Additives. Transactions of Society of Automotive Engineers of Japan, 2017. In FocusDOI: 10.11351/jsaeronbun.48.1341 
  2. Hendriks, L., et al., Characterization of a new ICP-TOFMS instrument with continuous and discrete introduction of solutions, Journal of Analytical Atomic Spectrometry, 2017.  In FocusDOI: 10.1039/C6JA00400H
  3. Burger, M., et al., Capabilities of laser ablation inductively coupled plasma time-of-flight mass spectrometry, Journal of Analytical Atomic Spectrometry, 2017. DOI: 10.1039/C7JA00236J
  4. Van Malderen, S., et al., Three-Dimensional reconstruction of the Tissue-Specific Multielemental Distribution within Ceriodaphnia dubia via Multimodal Registration Using Laser Ablation ICP-Mass Spectrometry and X-ray Spectroscopic Techniques, Analytical Chemistry, 2017. DOI: 10.1021/acs.analchem.7b00111
  5. Praetorius, A., et al., 2017, Single-particle multi-element fingerprinting (spMEF) using inductively-coupled plasma time-of-flight mass spectrometry (ICP-TOFMS) to identify engineered nanoparticles against the elevated natural background in soils, Environmental Science: Nano, 2017.  In Focus |DOI: 10.1039/C6EN00455E
  6. Bussweiler, Y., Olga Borovinskaya, Martin Tanner., Laser Ablation and inductively coupled plasma-time-of-flight mass spectrometry-A powerful combination for high-speed multielemental imaging on the micrometer scale.” Spectroscopy, 2017. In Focus | Link

2016

  1. Hao Wang et al., Simultaneous High Sensitivity Trace-Element and Isotopic Analysis of Gemstones Using Laser Ablation Inductively Coupled Plasma Time-of-Flight Mass Spectrometry, The Journal of Gemmology, 35(3), 2016.
  2. Wiedenbeck, M., Time-of-flight Mass Spectrometry: A New Tool for Laser Ablation Analyses, Elements Magazine, Oct. 2016. In Focus | Link
  3. Gundlach-Graham, Alexander, Toward faster and higher resolution LA–ICPMS imaging: on the co-evolution of LA cell design and ICPMS instrumentation, Analytical and Bioanalytical Chemistry, 2016.  In FocusDOI: 10.1007/s00216-015-9251-8

2015

  1. Harlaux, M., et al., Capabilities of sequential and quasi-simultaneous LA-ICPMS for the multi-element analysis of small quantity of liquids (pl to nl): insights from fluid inclusion analysis, Journal of Analytical Atomic Spectrometry, 2015.  In FocusDOI: 10.1039/C5JA00111K
  2. Gundlach-Graham, A., et al., High-speed, high-resolution, multi-elemental LA-ICP-TOFMS imaging: Part I instrumentation and two-dimensional imaging of geological samples, Analytical Chemistry, 2015. In FocusDOI:10.1021/acs.analchem.5b01196
  3. Burger, M., et al., High-speed, high-resolution, multi-elemental LA-ICP-TOFMS imaging: Part II. Critical evaluation of quantitative three-dimensional imaging of major, minor and trace elements in geological samples,  Analytical Chemistry, 2015. In FocusDOI: 10.1021/acs.analchem.5b01977

2014

  1. Borovinskaya, O., et al., Simultaneous Mass Quantification of Nanoparticles of Different Composition in a Mixture by Microdroplet Generator-ICPTOFMS,  Analytical Chemistry, 2014.  In FocusDOI: 10.1021/ac501150c
  2. Borovinskaya, O., et al., Diffusion- and velocity-driven spatial separation of analytes from single droplets entering an ICP off-axis,  J. Anal. At. Spectrom., 2014. DOI: 10.1039/c3ja50307k

2013

  1. Neubauer, Uta, Wie Forscher Nanopartikel in der Umwelt nachweisen, NZZ, 2013
  2. Borovinskaya, O., et al., A prototype of a new inductively coupled plasma timeof-flight mass spectrometer providing temporally resolved, multi-element detection of short signals generated by single particles and droplets, J. Anal. At. Spectrom., 2013. DOI: 10.1039/C2JA30227F

2008

  1. Tanner, Martin and D. Günther, A new ICP–TOFMS. Measurement and readout of mass spectra with 30 µs time resolution, applied to in-torch LA–ICP–MS,  Anal Bioanal Chem, 2008. DOI: 10.1007/s00216-008-1869-3

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icpTOF的背景知识